In **electrolysis**, the direction of flow of electrons and conventional current differs due to their opposite charges. Here's how it works:
### 1. **Electron Flow:**
- **Direction**: From the **negative electrode (cathode)** to the **positive electrode (anode)**.
- Electrons move through the external circuit, driven by the power supply. In an electrolytic cell, the **cathode** is the negative terminal (where reduction occurs), and the **anode** is the positive terminal (where oxidation occurs).
### 2. **Conventional Current Flow:**
- **Direction**: From the **positive electrode (anode)** to the **negative electrode (cathode)**.
- Conventional current is the flow of positive charge, which is defined as moving in the opposite direction to the flow of electrons. In electrolysis, this means the current flows from the **anode** (positive) to the **cathode** (negative) through the electrolyte.
### Summary of Directions:
- **Electron flow**: Cathode (negative) β Anode (positive)
- **Conventional current**: Anode (positive) β Cathode (negative)
This distinction is crucial because electrons (negatively charged particles) move toward the positive electrode, while conventional current (the hypothetical flow of positive charge) moves toward the negative electrode.