Generally, alloys have higher resistivity compared to pure metals. Here's a detailed explanation:
### Resistivity and Conductivity
- **Resistivity** is a measure of how strongly a material opposes the flow of electric current. It is the inverse of electrical conductivity, which measures how easily current can flow through a material.
### Pure Metals
- **Pure Metals**: Pure metals, like copper or silver, have relatively low resistivity. This is because the atoms in pure metals are arranged in a regular, repeating lattice structure, and the free electrons that carry the electric current encounter relatively few obstacles as they move through the material.
### Alloys
- **Alloys**: When metals are combined to form an alloy, the resulting material often has a more complex atomic structure. The presence of different metal atoms disrupts the regular lattice of the pure metal, introducing additional scattering centers for the electrons. This scattering increases the resistance to electron flow, thus increasing the resistivity.
### Reasons for Higher Resistivity in Alloys
1. **Atomic Disruptions**: Alloys typically have a mix of different sized atoms, which disrupt the regularity of the metal lattice. This disruption impedes the movement of free electrons, increasing resistivity.
2. **Impurities**: Alloys are often intentionally or unintentionally contaminated with other elements. These impurities also contribute to increased resistivity by scattering the conduction electrons.
3. **Grain Boundaries**: In many alloys, the microstructure includes grain boundaries or phases with different compositions. These grain boundaries and phases can impede the flow of electrons, increasing resistivity.
### Example
- **Copper vs. Bronze**: Copper, a pure metal, has low resistivity, making it an excellent conductor of electricity. Bronze, an alloy of copper and tin, has higher resistivity due to the disruption caused by the tin atoms.
In summary, while pure metals generally have lower resistivity, alloys tend to have higher resistivity due to the disruption of the regular lattice structure and the presence of additional scattering centers.