The terminal potential difference (or voltage) of a battery decreases as current increases due to the internal resistance of the battery. Here's a detailed explanation of why this happens:
### Battery Basics
A battery consists of one or more electrochemical cells that convert chemical energy into electrical energy. The battery has two key properties:
1. **Electromotive Force (EMF):** This is the maximum potential difference the battery can provide when no current is flowing (open circuit).
2. **Internal Resistance (r):** This is the resistance within the battery itself, caused by the materials and the chemical processes inside it.
### Understanding Terminal Potential Difference
When a battery is connected to an external circuit and current flows, the terminal potential difference (V_terminal) is the voltage measured across the battery terminals. It’s affected by both the EMF of the battery and the internal resistance.
### Ohm’s Law and Internal Resistance
The relationship between the EMF (E), terminal potential difference (V_terminal), internal resistance (r), and the current (I) flowing through the circuit can be described by the following equation:
\[ V_{\text{terminal}} = E - I \cdot r \]
Here's how this works in practice:
1. **When No Current Flows:** If the circuit is open and no current flows, the terminal potential difference is equal to the EMF of the battery.
2. **When Current Flows:** As current starts to flow through the battery, it encounters the internal resistance. According to Ohm's Law, the voltage drop due to the internal resistance is given by \( I \cdot r \), where \( I \) is the current and \( r \) is the internal resistance.
3. **Decrease in Terminal Potential Difference:** Because of this internal voltage drop, the terminal potential difference decreases. So, if the current increases, the voltage drop across the internal resistance increases as well, causing a greater reduction in the terminal voltage.
### Practical Example
Consider a battery with an EMF of 12 volts and an internal resistance of 1 ohm. If no current is flowing, the terminal voltage is 12 volts.
- **If a small current of 1 ampere flows:**
\[ V_{\text{terminal}} = 12\text{V} - (1\text{A} \times 1\text{Ω}) = 11\text{V} \]
- **If a larger current of 5 amperes flows:**
\[ V_{\text{terminal}} = 12\text{V} - (5\text{A} \times 1\text{Ω}) = 7\text{V} \]
In this example, as the current increases from 1 ampere to 5 amperes, the terminal potential difference drops from 11 volts to 7 volts.
### Summary
The terminal potential difference of a battery decreases as current increases primarily due to the internal resistance of the battery. The internal resistance causes a voltage drop that increases with current, leading to a lower terminal voltage compared to the EMF when the battery is not supplying current.