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Is electromotive force is the maximum potential difference between the terminals of a battery?

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Electromotive force (emf) is often discussed in the context of batteries and electrical circuits, but it’s important to clarify what it means and how it relates to the potential difference (voltage) across the terminals of a battery.

### Definition of Electromotive Force (emf)

Electromotive force (emf) is defined as the energy provided by a source of electrical energy per unit charge. In simpler terms, it represents the ability of a battery or any other energy source to push electrical charge through a circuit. It is measured in volts (V) and is denoted by the symbol \( \mathcal{E} \).

### Relationship to Potential Difference

1. **Maximum Potential Difference**: The emf of a battery is indeed the maximum potential difference between its terminals when no current is flowing. This is referred to as the open-circuit voltage. When you measure the voltage across the terminals of a battery that is not connected to a circuit (or load), you will see this maximum value.

2. **Loaded Conditions**: When the battery is connected to a circuit and current flows, the actual potential difference (or terminal voltage) across the battery’s terminals may be less than the emf. This reduction occurs due to internal resistance within the battery. The relationship can be described by the formula:

   \[
   V = \mathcal{E} - I \cdot r
   \]

   Here:
   - \( V \) is the terminal voltage (the potential difference when a load is connected).
   - \( \mathcal{E} \) is the electromotive force (the open-circuit voltage).
   - \( I \) is the current flowing through the circuit.
   - \( r \) is the internal resistance of the battery.

3. **Internal Resistance**: Every battery has some internal resistance due to the materials and chemical processes inside it. When current flows, this internal resistance causes a voltage drop, which reduces the effective voltage available to the external circuit. Therefore, under load, the potential difference you can measure across the terminals will be less than the emf.

### Summary

To summarize, while the emf of a battery can be considered the maximum potential difference between its terminals when no current flows, it is not the same as the potential difference you would measure when the battery is powering a device or circuit. In practical applications, always consider that the effective voltage can be lower than the emf due to the effects of internal resistance when a current is drawn from the battery.
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Yes, electromotive force (EMF) represents the maximum potential difference between the terminals of a battery when no current is flowing (i.e., under open-circuit conditions). EMF is the energy supplied by a source per unit charge, which drives the flow of charge in a circuit.

However, once a current starts to flow, the actual potential difference (terminal voltage) across the battery will be less than the EMF due to internal resistance within the battery. This drop in voltage happens because part of the EMF is used to overcome the battery's internal resistance.
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