A lead storage battery, also known as a lead-acid battery, is considered a secondary cell because it is rechargeable. To understand why it falls into this category, it's useful to distinguish between primary and secondary cells:
### Primary Cells
- **Non-Rechargeable**: Primary cells are designed for single-use and cannot be recharged. Once the chemical reactants are exhausted, the cell cannot be used again.
- **Examples**: Common examples include alkaline batteries and zinc-carbon batteries. These are typically used in devices like remote controls, flashlights, and clocks.
### Secondary Cells
- **Rechargeable**: Secondary cells, in contrast, are designed to be recharged and reused multiple times. They can undergo numerous charge and discharge cycles without significant loss of performance.
- **Examples**: Examples include lithium-ion batteries, nickel-cadmium (NiCd) batteries, and lead-acid batteries.
### Lead-Acid Battery as a Secondary Cell
1. **Rechargeable Mechanism**: Lead-acid batteries are rechargeable due to the reversible chemical reactions that occur during discharge and recharge cycles. When the battery discharges, the lead dioxide (PbO₂) at the positive plate reacts with sulfuric acid (H₂SO₄) to form lead sulfate (PbSO₄) and water. During charging, an external electrical current reverses this process, converting lead sulfate and water back into lead dioxide and sulfuric acid.
2. **Construction and Chemistry**: A lead-acid battery consists of lead dioxide (PbO₂) as the positive plate, sponge lead (Pb) as the negative plate, and a sulfuric acid (H₂SO₄) electrolyte. The battery's ability to be recharged is a result of the reversible nature of the chemical reactions between these materials.
3. **Applications**: Lead-acid batteries are commonly used in applications where high power output and reliability are required, such as in automotive starter batteries, uninterruptible power supplies (UPS), and backup power systems. Their ability to be recharged makes them suitable for these uses, as they can be repeatedly charged and discharged over their lifespan.
4. **Cycle Life and Efficiency**: Although lead-acid batteries are not as efficient or have as long a cycle life as some modern secondary cells like lithium-ion batteries, they remain popular due to their cost-effectiveness and robust performance. They are particularly valued in applications where high current output and durability are necessary.
In summary, the lead-acid battery is considered a secondary cell because it is designed to be recharged and reused multiple times, which is a defining characteristic of secondary cells as opposed to primary cells.