When a material becomes polarized, the electric field inside and around it is affected by the rearrangement of electric charges within the material. This process of polarization, where the charges shift slightly in response to an external electric field, changes the overall behavior of the electric field in the following ways:
### 1. **Polarization and Bound Charges**
- In a polarized material, the external electric field causes **bound charges** to form, meaning charges that don't leave the material but shift within atoms or molecules. Positive and negative charges move slightly apart within each molecule or atom, creating tiny dipoles.
- The polarization results in **surface bound charges** on the material’s boundary. Positive bound charges accumulate on one surface, while negative bound charges accumulate on the opposite surface.
- These bound charges produce their own internal electric field, which opposes the external applied electric field.
### 2. **Reduction of the Internal Electric Field**
- The internal electric field created by these polarized bound charges works in opposition to the external electric field. As a result, the **net electric field** inside the material is reduced compared to the external electric field.
- The stronger the polarization (i.e., the larger the dipoles inside the material), the more the internal electric field cancels out the external field.
### 3. **Electric Displacement Field (D-field)**
- To describe the combined effect of free charges (from external sources) and bound charges (from polarization), physicists use the **electric displacement field** \( \mathbf{D} \). This is related to the electric field \( \mathbf{E} \) and the polarization \( \mathbf{P} \) by the equation:
\[
\mathbf{D} = \varepsilon_0 \mathbf{E} + \mathbf{P}
\]
where \( \varepsilon_0 \) is the permittivity of free space.
- In materials, \( \mathbf{D} \) accounts for both the external field and the polarization effects, helping to understand the electric field behavior when dielectric (polarizable) materials are involved.
### 4. **Effect on Capacitance (Dielectric Materials)**
- When a dielectric material is placed between the plates of a capacitor, the polarization of the dielectric reduces the effective electric field inside the capacitor. This increases the capacitor’s ability to store charge, thus increasing the **capacitance**.
- The relationship between the permittivity of the dielectric material (a measure of how easily it polarizes) and the electric field is captured by the material's **relative permittivity** \( \varepsilon_r \) or **dielectric constant**. A higher dielectric constant means the material polarizes more, leading to greater reduction in the internal field and higher capacitance.
### 5. **In Homogeneous and Inhomogeneous Materials**
- In **homogeneous materials** (materials with uniform composition), polarization is uniform, and the internal electric field is reduced evenly throughout the material.
- In **inhomogeneous materials** (where the material properties vary), the polarization and internal electric field may vary spatially, leading to more complex electric field distributions.
### 6. **Dielectric Breakdown**
- When the external electric field becomes too strong, the material can no longer sustain the polarization, leading to dielectric breakdown. In this case, the internal electric field can no longer counteract the external field, and the material may become conductive, allowing charges to flow freely.
### Summary of Key Effects:
- **Polarization opposes the external field**, reducing the net electric field inside the material.
- **Surface bound charges** are created, generating their own internal field.
- **Capacitance increases** in dielectric materials due to polarization.
- The **electric displacement field** \( \mathbf{D} \) is used to account for both free and bound charge effects.
Thus, the electric field due to polarization is always influenced by the material's response to an external field, leading to a more complex overall field. Polarization reduces the net electric field inside a dielectric, enhances the material's ability to store charge, and affects the overall electrical properties of devices like capacitors.