Electromotive force (EMF) and potential difference are fundamental concepts in electricity and electronics, and while they are related, they refer to different things. Here’s a detailed explanation of each:
### Electromotive Force (EMF)
1. **Definition**: EMF is a measure of the energy provided by a source, like a battery or generator, to drive electric current through a circuit. It represents the maximum potential difference that the source can provide when no current is flowing (open circuit condition).
2. **Origin**: EMF is generated by various sources like batteries, generators, and solar cells. In a battery, for example, chemical reactions within the cells produce a voltage that drives electrons through a circuit. In generators, mechanical energy is converted into electrical energy.
3. **Measurement**: EMF is typically measured in volts (V), just like potential difference. However, it’s important to note that EMF is the theoretical maximum voltage of the source.
4. **Formula**: If \( E \) represents EMF, the relationship can be given by \( E = V_{oc} \), where \( V_{oc} \) is the open circuit voltage.
5. **Internal Resistance**: Real sources of EMF have internal resistance. This means that when current flows, the actual voltage available across the terminals is less than the EMF due to the internal voltage drop.
### Potential Difference (Voltage)
1. **Definition**: Potential difference, or simply voltage, is the measure of the energy difference per unit charge between two points in a circuit. It drives the flow of current through the circuit and is what you actually measure across components when current is flowing.
2. **Origin**: Potential difference arises due to the difference in electric potential energy between two points. In a circuit, this difference is caused by sources of EMF and is influenced by the components of the circuit (like resistors, capacitors, etc.).
3. **Measurement**: Like EMF, potential difference is also measured in volts (V). However, this measurement is dependent on the current flow and the components in the circuit.
4. **Formula**: If \( V \) represents potential difference, it can be expressed as \( V = I \times R \), where \( I \) is the current and \( R \) is the resistance through which the current flows.
5. **Circuit Conditions**: The potential difference across a component can be different from the EMF of the source due to the internal resistance of the source and other factors in the circuit.
### Key Differences
1. **Nature**: EMF is an idealized measure of a source’s ability to drive current, while potential difference is the actual voltage experienced across components when current is flowing.
2. **Condition**: EMF is defined when no current is flowing (open circuit), whereas potential difference is measured when current is flowing (closed circuit).
3. **Effect of Internal Resistance**: In a real circuit, the potential difference across a source is less than its EMF due to internal resistance. EMF is the total voltage provided by the source, while potential difference takes into account the voltage drop across internal resistances and other circuit elements.
4. **Application**: EMF describes the capability of a source, whereas potential difference describes the practical voltage across components in a functioning circuit.
In summary, EMF is the maximum potential that a source can deliver, while potential difference is the actual voltage drop across components in a circuit.