The relationship between electric flux density (\(\mathbf{D}\)) and volume charge density (\(\rho\)) is given by Gauss's law in the context of electromagnetism.
Gauss's law states that the divergence of the electric flux density \(\mathbf{D}\) is equal to the volume charge density \(\rho\):
\[ \nabla \cdot \mathbf{D} = \rho \]
In a vacuum or free space, where there are no free charges, the electric flux density \(\mathbf{D}\) is related to the electric field \(\mathbf{E}\) by:
\[ \mathbf{D} = \varepsilon_0 \mathbf{E} \]
where \(\varepsilon_0\) is the permittivity of free space.
In materials with dielectric properties, the relationship is:
\[ \mathbf{D} = \varepsilon \mathbf{E} \]
where \(\varepsilon\) is the permittivity of the material.
The volume charge density \(\rho\) is the source term in Gauss's law and represents the amount of electric charge per unit volume in a region of space.