Insulation resistance decreases when temperatures increase due to the changes in the physical and chemical properties of the insulating material, specifically related to molecular activity and electrical conductivity. Let’s break down the reasons in detail:
### 1. **Increased Molecular Activity:**
- **Thermal Agitation:** When temperature increases, the molecules inside the insulating material gain more thermal energy and start vibrating more vigorously. This increased molecular motion disrupts the structure of the insulation, allowing for more free movement of electrons. Normally, an insulator restricts electron flow, but at higher temperatures, these vibrations provide energy to electrons, making them more likely to break free and conduct electricity.
- **Reduced Molecular Bond Strength:** With increased temperature, the bonds holding the insulating material’s molecules together weaken slightly. As a result, the material becomes less effective at blocking the movement of charge carriers (like electrons or ions).
### 2. **Increased Leakage Currents:**
- **Higher Charge Carrier Mobility:** As the temperature rises, the mobility of charge carriers (such as electrons and ions) increases within the insulating material. Since insulation is designed to block current, the presence of any free carriers can lead to leakage currents. At higher temperatures, the increased energy of the carriers allows more of them to traverse through the insulation, reducing its overall resistance.
- **Thermal Generation of Charge Carriers:** In many insulating materials, especially in polymeric and organic types, increased heat can lead to thermal generation of free charge carriers. These carriers contribute to leakage currents, further reducing the insulation resistance.
### 3. **Breakdown of Chemical Structure:**
- **Degradation of Insulating Materials:** Over time and with increased heat, some insulating materials degrade or break down. For instance, organic insulators like plastics, rubber, or even some varnishes, can experience chemical changes when exposed to high temperatures. These changes can result in cracks or micro-voids, allowing moisture to enter or creating paths for electrical conduction, thus lowering the insulation resistance.
### 4. **Moisture Absorption:**
- **Condensation and Moisture Penetration:** In some materials, increased temperature can cause the insulation to expand, allowing for moisture ingress if the surrounding environment is humid. Moisture is a good conductor of electricity, so any absorbed water will reduce the insulation resistance.
### 5. **Intrinsic Conductivity of Insulation Material:**
- **Intrinsic Semiconductor-Like Behavior:** Some insulating materials exhibit behavior similar to semiconductors at elevated temperatures. In semiconductors, as the temperature increases, the number of charge carriers increases due to the excitation of electrons from the valence band to the conduction band. While insulators have a large energy gap between these bands, a significant temperature rise can still excite some electrons, leading to a small but measurable increase in conductivity and a corresponding decrease in resistance.
### Mathematical Relationship:
The change in insulation resistance with temperature is often expressed using a rule of thumb: **for every 10°C rise in temperature, the insulation resistance halves**. This is due to the exponential relationship between temperature and the mobility of charge carriers, and is often represented by the following equation:
\[
R(T) = R_0 \cdot e^{-\alpha (T - T_0)}
\]
Where:
- \( R(T) \) is the insulation resistance at temperature \( T \),
- \( R_0 \) is the insulation resistance at a reference temperature \( T_0 \),
- \( \alpha \) is a material-specific constant that describes how fast the resistance changes with temperature,
- \( e \) is Euler's number (approximately 2.718).
### Conclusion:
In summary, the decrease in insulation resistance with increasing temperature is primarily due to increased molecular motion, increased leakage currents, possible degradation of the insulating material, and the generation of additional charge carriers. This behavior highlights the importance of selecting the right insulation material for the operating temperature range in electrical systems to ensure reliable performance and safety.