Lithium batteries can be either primary or secondary, depending on their design and intended use.
### Primary Lithium Batteries
**Definition:** Primary lithium batteries are non-rechargeable. Once the battery's energy is depleted, it cannot be recharged and must be replaced with a new one.
**Characteristics:**
- **Energy Density:** They typically have a high energy density, which means they can store a lot of energy relative to their size and weight.
- **Long Shelf Life:** These batteries have a long shelf life, often retaining their charge for several years when stored properly.
- **Applications:** They are commonly used in devices that require a long-lasting power source but are not frequently recharged, such as smoke detectors, watches, and some medical devices.
**Types of Primary Lithium Batteries:**
- **Lithium Manganese Dioxide (Li/MnO₂):** Often used in household electronics and medical devices.
- **Lithium Iron Disulfide (Li/FeS₂):** Known for its high energy density and used in high-performance applications like digital cameras.
### Secondary Lithium Batteries
**Definition:** Secondary lithium batteries are rechargeable. They can be recharged multiple times and used repeatedly, making them more cost-effective in the long run for devices that are used frequently.
**Characteristics:**
- **Rechargeable:** They can be charged and discharged many times, depending on the battery's quality and usage conditions.
- **High Capacity:** Often used in applications requiring frequent recharging, such as laptops, smartphones, and electric vehicles.
- **Cycle Life:** The number of charge-discharge cycles they can undergo before their capacity significantly diminishes varies by battery chemistry and usage conditions.
**Types of Secondary Lithium Batteries:**
- **Lithium-Ion (Li-ion):** Widely used in consumer electronics (phones, laptops), electric vehicles, and renewable energy systems. Known for high energy density and relatively long cycle life.
- **Lithium Polymer (LiPo):** A variation of Li-ion technology with a flexible, polymer electrolyte. Common in applications where lightweight and custom shapes are important, like in drones and some portable electronics.
- **Lithium Iron Phosphate (LiFePO₄):** Known for its safety and long cycle life. Used in applications like electric vehicles and stationary energy storage.
### Summary
- **Primary Lithium Batteries**: Non-rechargeable, high energy density, used for long-term single-use applications.
- **Secondary Lithium Batteries**: Rechargeable, used in applications with frequent charging needs, high capacity, and longer cycle life.
Understanding these distinctions helps in selecting the right type of lithium battery for a specific application, balancing factors like cost, energy needs, and reusability.