In a closed electrical circuit, the **potential difference (V)** across the terminals of a power source (like a battery) is always less than the **electromotive force (emf, ε)** due to energy losses within the source itself, primarily caused by **internal resistance (r)**. Here's a detailed explanation of why this happens:
### 1. **What is Electromotive Force (emf)?**
The electromotive force (emf) is the total energy per unit charge that a power source, such as a battery or generator, can provide. It is the ideal potential difference across the terminals of the source when no current is flowing, meaning in an **open circuit**.
Mathematically, it’s defined as the work done to move a charge around the entire circuit, including both the external and internal parts of the circuit. Therefore, emf is the maximum potential difference that can be obtained from a source.
### 2. **What is Potential Difference (V)?**
The potential difference (or voltage) across the terminals of a power source in a **closed circuit** (when current is flowing) is the actual voltage available to drive current through the external circuit (resistors, devices, etc.). This is the usable voltage that we can measure across the external components connected to the circuit.
### 3. **Internal Resistance (r)**
Every real battery or power source has some internal resistance due to the materials it’s made of and the chemical processes that generate electrical energy. This **internal resistance (r)** is the opposition to current flow inside the battery itself, which causes energy to be lost as heat when the current flows.
This is why we cannot get the full emf when the circuit is closed and current flows. The energy that could have been provided to the external circuit is partially lost within the battery due to this internal resistance.
### 4. **Energy Loss in a Closed Circuit**
When the circuit is closed, the current (I) flows through both the internal resistance (r) and the external load (resistor, light bulb, etc.). According to Ohm's Law, the voltage drop across the internal resistance is:
\[
\text{Voltage drop across internal resistance} = I \times r
\]
This voltage drop is subtracted from the emf to give the actual potential difference across the terminals of the battery, which is less than the emf.
### 5. **Equation of the Closed Circuit**
The relationship between emf, internal resistance, and potential difference in a closed circuit can be described by the equation:
\[
\text{emf} = V + I \times r
\]
Where:
- **emf** is the electromotive force,
- **V** is the potential difference across the external circuit (what’s available for the external components),
- **I** is the current in the circuit,
- **r** is the internal resistance of the power source.
Rearranging the formula, we get:
\[
V = \text{emf} - I \times r
\]
This equation shows that the actual potential difference (V) is always less than the emf by an amount equal to the voltage drop due to the internal resistance \( (I \times r) \).
### 6. **Conclusion: Why is Potential Difference Less Than emf?**
In a closed circuit, some of the energy provided by the source (the emf) is "used up" in overcoming the internal resistance of the source itself. This results in a voltage drop inside the source, and thus the potential difference across the terminals of the source (what is available for the external circuit) is always less than the total emf.
If there were no internal resistance (which is an ideal but not realistic case), the potential difference would be equal to the emf. However, in practical, real-world situations, internal resistance always causes the potential difference to be less than the emf. The larger the internal resistance or the current, the greater the difference between the emf and the potential difference.