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What happened in the battery to cause the terminal potential difference to be slightly less than the emf of the battery?

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In a battery, the terminal potential difference can be slightly less than the electromotive force (EMF) due to internal resistance. Here’s a detailed explanation of why this occurs:

### 1. **Understanding EMF and Terminal Potential Difference**

- **EMF (Electromotive Force):** This is the maximum potential difference that the battery can provide when no current is flowing. It represents the energy provided per unit charge by the battery's chemical reactions or other energy conversion processes.

- **Terminal Potential Difference:** This is the voltage measured across the terminals of the battery when it is connected to a circuit and a current is flowing. It is the actual voltage available to the external circuit.

### 2. **Internal Resistance of the Battery**

- **Internal Resistance:** Every battery has some internal resistance, which arises from the materials and components inside the battery. This internal resistance causes a voltage drop within the battery when current flows through it.

### 3. **Why the Terminal Potential Difference is Less**

Here’s the step-by-step process that explains the difference:

1. **Current Flow and Internal Resistance:** When the battery is connected to a circuit and current flows, the internal resistance causes a voltage drop within the battery. This internal resistance is denoted as \( r \).

2. **Voltage Drop Calculation:** The voltage drop across the internal resistance can be calculated using Ohm’s Law. If \( I \) is the current flowing through the battery, the voltage drop across the internal resistance is \( I \times r \).

3. **Terminal Potential Difference Formula:** The terminal potential difference \( V_{terminal} \) is the EMF minus the voltage drop due to internal resistance. Mathematically, it can be expressed as:
   \[
   V_{terminal} = \text{EMF} - I \times r
   \]
   Here, \( \text{EMF} \) is the total potential that the battery can provide, and \( I \times r \) is the internal voltage drop.

### 4. **Practical Impact**

- **Loaded vs. Unloaded Battery:** When no current flows (open circuit condition), the terminal potential difference equals the EMF. However, as soon as a load is connected and current begins to flow, the terminal potential difference decreases slightly due to the internal resistance.

- **Battery Performance:** This internal resistance can affect the performance of the battery, especially under high current loads. Batteries with high internal resistance will have a more significant drop in terminal potential difference under load.

### 5. **Summary**

In summary, the terminal potential difference is slightly less than the EMF of the battery because of the internal resistance of the battery. When current flows, the internal resistance causes a voltage drop inside the battery, which reduces the voltage available at the terminals compared to the EMF.

Understanding this concept is important for designing and using electrical circuits, as it helps in predicting how batteries will behave under different loads and ensuring that devices receive the appropriate voltage.
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The terminal potential difference of a battery is slightly less than its electromotive force (EMF) due to the internal resistance of the battery. Here’s a detailed explanation of the phenomena involved:

### 1. **Understanding EMF and Terminal Potential Difference**

- **EMF (Electromotive Force)**: This is the maximum potential difference between the terminals of a battery when no current is flowing. It represents the energy per unit charge supplied by the battery's internal chemical reactions.

- **Terminal Potential Difference**: This is the actual potential difference across the battery's terminals when current is flowing through the circuit. It’s the voltage available to the external circuit.

### 2. **Internal Resistance**

Batteries have internal resistance, which is a measure of how much the battery resists the flow of current internally. This resistance is due to the battery’s materials and construction, including the electrolyte, electrodes, and other components.

### 3. **Effect of Internal Resistance**

When a current \( I \) flows through a battery with internal resistance \( r \), the voltage drop \( V_r \) across the internal resistance is given by Ohm’s law:

\[ V_r = I \cdot r \]

### 4. **Terminal Potential Difference Calculation**

The terminal potential difference \( V_{terminal} \) is the EMF \( E \) minus the voltage drop across the internal resistance:

\[ V_{terminal} = E - I \cdot r \]

### 5. **Why Terminal Potential Difference is Less**

- **When No Current Flows**: If no current flows (open circuit), the terminal potential difference equals the EMF because there’s no voltage drop across the internal resistance.

- **When Current Flows**: As soon as a current flows through the battery, the internal resistance causes a voltage drop. This results in the terminal potential difference being slightly less than the EMF of the battery.

### **Example**

Imagine a battery with an EMF of 12 volts and an internal resistance of 0.5 ohms. If the battery supplies a current of 2 amperes, the voltage drop across the internal resistance is:

\[ V_r = I \cdot r = 2 \, \text{A} \times 0.5 \, \Omega = 1 \, \text{V} \]

Thus, the terminal potential difference \( V_{terminal} \) will be:

\[ V_{terminal} = E - V_r = 12 \, \text{V} - 1 \, \text{V} = 11 \, \text{V} \]

This reduction in the terminal potential difference due to internal resistance is a common characteristic of practical batteries.
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