When comparing the electromotive force (emf) of different cells, a potentiometer is often preferred over a voltmeter for several reasons, which we can explore in detail:
### 1. **Measurement Technique**
- **Potentiometer**: A potentiometer measures the emf by balancing it against a known voltage without drawing any current from the cell being tested. It achieves this by setting up a circuit where the potential drop across a known resistor is adjusted until it matches the emf of the cell. This means that the reading is purely a function of the voltages involved, allowing for very precise measurements.
- **Voltmeter**: A voltmeter, on the other hand, measures the voltage of a cell by connecting across its terminals and drawing current from it. The internal resistance of the voltmeter, though high, still affects the measurement. This current flow can lead to a voltage drop across the internal resistance of the cell, resulting in a lower reading than the actual emf, especially for cells with high internal resistance.
### 2. **Accuracy and Sensitivity**
- **High Accuracy**: The potentiometer provides a high degree of accuracy because it avoids loading the cell. This means that the reading reflects the true emf without the influence of any internal resistance, leading to more reliable results.
- **Sensitivity to Small Changes**: Potentiometers can be designed to measure very small differences in voltage, which makes them more sensitive than standard voltmeters. This is particularly useful when comparing cells with very similar emfs.
### 3. **Calibration and Comparison**
- **Direct Comparison**: A potentiometer allows for a direct comparison between the emf of two cells by adjusting the known voltage until it matches the unknown. This process doesn't require recalibrating the instrument for each measurement, making it efficient.
- **Calibration Ease**: Potentiometers can be calibrated against a standard voltage source, ensuring that the measurements are consistent and accurate across different setups and conditions.
### 4. **Effect of Internal Resistance**
- **Minimized Errors**: Because a potentiometer does not draw current from the cell being measured, it minimizes errors due to the internal resistance of the cell. In contrast, voltmeters can produce readings that are affected by this internal resistance, especially in cases where the cell’s internal resistance is significant.
### 5. **Applications in Experimental Physics**
- **Ideal for Laboratory Settings**: Potentiometers are widely used in laboratory settings where precision is crucial. They are often employed in experiments involving the comparison of different voltage sources, calibration of instruments, and in educational settings to demonstrate principles of electricity.
### Conclusion
In summary, while voltmeters are useful and convenient for general voltage measurements, a potentiometer provides superior accuracy, sensitivity, and reliability when comparing the emf of different cells. Its ability to avoid loading the circuit makes it the preferred choice in situations where precise voltage measurements are critical.