The electromotive force (emf) of a battery is defined as the potential difference across the terminals of the battery when no current is flowing, whereas the terminal potential difference is the voltage measured across the terminals of the battery when it is under load (i.e., when current is flowing).
The emf of a battery is equal to its terminal potential difference in the following conditions:
1. **No Load Condition**: When the battery is not supplying any current (open-circuit condition), the emf equals the terminal potential difference. This is because there are no voltage drops due to internal resistance.
2. **Ideal Conditions**: In an ideal battery (which has no internal resistance), the emf will always equal the terminal potential difference, regardless of the load.
3. **Zero Current**: If the current flowing through the circuit is zero (e.g., a switch is open), then the terminal voltage is equal to the emf.
When the battery is supplying current, the terminal potential difference will be less than the emf due to the voltage drop across the internal resistance of the battery, which can be described by the equation:
\[
V = \text{emf} - I \cdot r
\]
where:
- \(V\) is the terminal potential difference,
- \(I\) is the current flowing through the circuit,
- \(r\) is the internal resistance of the battery.
In summary, the emf of a battery is equal to its terminal potential difference only when there is no current flowing or in ideal conditions without internal resistance.