It seems like there might be a misunderstanding in the question. In most practical cases, the terminal voltage of a battery is actually less than its electromotive force (EMF), not more. Let’s break down why this is the case.
### Key Concepts
1. **Electromotive Force (EMF):** EMF is the maximum potential difference between the terminals of a battery when no current is flowing. It represents the battery’s ability to drive current through a circuit.
2. **Terminal Voltage:** Terminal voltage is the actual voltage available across the terminals of the battery when current is flowing. It is the voltage you measure when the battery is connected to a load and current is flowing through the circuit.
### Why Terminal Voltage is Less than EMF
When a battery is providing current to a circuit, the terminal voltage is affected by the internal resistance of the battery. Here’s how it works:
1. **Internal Resistance:** Every real battery has some internal resistance (denoted as \( r_{\text{int}} \)). This resistance causes a voltage drop inside the battery when current flows.
2. **Ohm’s Law and Voltage Drop:** According to Ohm’s Law, the voltage drop across the internal resistance of the battery is given by \( V_{\text{drop}} = I \cdot r_{\text{int}} \), where \( I \) is the current flowing through the circuit. This voltage drop occurs within the battery itself.
3. **Terminal Voltage Calculation:** The terminal voltage (\( V_{\text{term}} \)) can be found by subtracting the voltage drop across the internal resistance from the EMF of the battery. Mathematically, it’s expressed as:
\[
V_{\text{term}} = \text{EMF} - I \cdot r_{\text{int}}
\]
This means that the terminal voltage will always be less than the EMF because of the internal voltage drop.
### Practical Example
Consider a battery with an EMF of 12 volts and an internal resistance of 1 ohm. If the battery is supplying a current of 2 amperes, the voltage drop due to internal resistance is:
\[
V_{\text{drop}} = I \cdot r_{\text{int}} = 2 \text{ A} \cdot 1 \text{ }\Omega = 2 \text{ V}
\]
Thus, the terminal voltage is:
\[
V_{\text{term}} = \text{EMF} - V_{\text{drop}} = 12 \text{ V} - 2 \text{ V} = 10 \text{ V}
\]
### Conclusion
In summary, the terminal voltage of a battery is typically less than its EMF due to the internal resistance causing a voltage drop when current flows. The EMF represents the ideal maximum voltage when no current is flowing, while the terminal voltage represents the practical voltage available under load.