Lead-acid batteries can fail for several reasons, often related to their chemistry, usage, or maintenance. Here are the most common causes:
### 1. **Sulfation**
- **Description**: This occurs when the lead sulfate crystals that form on the battery plates during discharge become hard and resistant to reconversion back to active material during charging.
- **Cause**: Undercharging or leaving the battery in a discharged state for extended periods causes sulfation, which reduces the battery's ability to hold a charge.
### 2. **Overcharging**
- **Description**: Overcharging happens when the battery is charged for too long or at too high a voltage.
- **Cause**: It leads to excessive heat and gassing, which can cause water loss in the electrolyte, damage to the plates, and eventually lead to battery failure.
### 3. **Water Loss (Dry-Out)**
- **Description**: The electrolyte in lead-acid batteries is a mixture of sulfuric acid and water. If the water evaporates due to heat or overcharging, the electrolyte level drops.
- **Cause**: Low electrolyte levels can expose the lead plates to air, causing oxidation and irreversible damage.
### 4. **Corrosion**
- **Description**: Corrosion of the battery terminals, plates, or connections can lead to increased internal resistance and reduced battery performance.
- **Cause**: This typically occurs due to the release of hydrogen gas during charging, especially in flooded lead-acid batteries.
### 5. **Plate Shedding**
- **Description**: Over time, the active material on the lead plates can shed due to repeated cycling, vibration, or overcharging.
- **Cause**: This material falls to the bottom of the battery and can short out the cells, reducing the overall capacity of the battery.
### 6. **Stratification**
- **Description**: In flooded lead-acid batteries, the electrolyte can stratify, meaning the acid becomes more concentrated at the bottom of the battery and more dilute at the top.
- **Cause**: This usually occurs if the battery is undercharged or used in a low-power application for a long time. Stratification results in uneven charging and can lead to battery failure.
### 7. **Temperature Extremes**
- **Description**: Lead-acid batteries are sensitive to temperature. High temperatures accelerate internal corrosion, while low temperatures reduce the battery’s ability to deliver current.
- **Cause**: Exposure to prolonged heat leads to faster degradation, while cold weather can make starting an engine difficult and lead to higher wear.
### 8. **Deep Discharge**
- **Description**: Lead-acid batteries are not designed to be deeply discharged on a regular basis, especially not below 50% of their capacity.
- **Cause**: Repeated deep discharges cause stress on the battery plates and reduce the overall lifespan of the battery.
### 9. **Vibration or Mechanical Damage**
- **Description**: Physical damage or constant vibration can weaken internal connections, causing short circuits or damage to the battery plates.
- **Cause**: This is common in vehicle batteries that are exposed to rough terrain or poor mounting systems.
### 10. **Aging**
- **Description**: Even with proper care, lead-acid batteries have a finite lifespan. Over time, chemical reactions inside the battery cause gradual degradation.
- **Cause**: Most lead-acid batteries last between 3 to 5 years under normal conditions.
To prolong the life of a lead-acid battery, proper maintenance is crucial, including avoiding deep discharge, ensuring adequate charging, and keeping the battery clean and free from corrosion.