Semiconductors are materials that have electrical conductivity between that of a conductor and an insulator. They are fundamental in electronics because they can control the flow of current. The two main types of semiconductors are **intrinsic** and **extrinsic** semiconductors. Here's a breakdown:
### 1. **Intrinsic Semiconductors**
- **Definition**: Pure semiconductors without any impurities.
- **Common materials**: Silicon (Si) and Germanium (Ge).
- **Properties**:
- The electrical properties are solely determined by the semiconductor material itself.
- At absolute zero, intrinsic semiconductors behave like insulators, but at room temperature, they have a small number of charge carriers (electrons and holes).
- **Conductivity**: The number of charge carriers (electrons and holes) is equal, i.e., **n = p**, where **n** is the electron concentration, and **p** is the hole concentration.
### 2. **Extrinsic Semiconductors**
- **Definition**: Semiconductors that have been "doped" with impurities to improve their conductivity. There are two types of extrinsic semiconductors, **n-type** and **p-type**.
#### a) **n-Type Semiconductors**
- **Doping Element**: Elements from group V of the periodic table (like Phosphorus, Arsenic, or Antimony) are added to the pure semiconductor (usually Silicon or Germanium).
- **Extra Electrons**: These elements introduce an extra electron, leading to an excess of negative charge carriers (electrons).
- **Majority carriers**: Electrons are the majority charge carriers, while holes are the minority carriers.
- **Conductivity**: Increases due to the availability of extra electrons.
#### b) **p-Type Semiconductors**
- **Doping Element**: Elements from group III of the periodic table (like Boron, Gallium, or Indium) are added.
- **Holes**: These elements introduce a deficiency of electrons (or "holes") in the lattice.
- **Majority carriers**: Holes are the majority charge carriers, while electrons are the minority carriers.
- **Conductivity**: Increases due to the movement of holes.
### 3. **Compound Semiconductors**
- These are made from two or more elements from different groups in the periodic table. Examples include Gallium Arsenide (GaAs) and Indium Phosphide (InP).
- **Application**: Often used in high-speed devices, LEDs, and laser diodes due to superior properties compared to elemental semiconductors like silicon.
### Summary
- **Intrinsic Semiconductors**: Pure materials without impurities (e.g., silicon, germanium).
- **Extrinsic Semiconductors**: Doped materials with impurities to increase conductivity, further classified as **n-type** (electron-rich) and **p-type** (hole-rich).
- **Compound Semiconductors**: Made from multiple elements, useful for specific applications like optoelectronics.
Each type of semiconductor has unique properties and applications, making them essential to different electronic devices like transistors, diodes, and integrated circuits.