Electromotive Force (EMF) and potential difference (voltage) are related concepts, but they are not the same. Here’s a detailed explanation of each and how they differ:
### Electromotive Force (EMF)
- **Definition**: EMF is a measure of the energy provided by a source per unit charge. It is the maximum potential difference that a source, like a battery or generator, can provide when no current is flowing. Essentially, EMF is what drives the current around a circuit.
- **Source**: EMF is generated by sources such as batteries, generators, and photovoltaic cells. In these sources, chemical reactions (in batteries), mechanical energy (in generators), or light energy (in solar cells) are converted into electrical energy.
- **Measurement**: EMF is measured in volts (V) and represents the work done per unit charge to move electrons from one terminal to the other.
### Potential Difference (Voltage)
- **Definition**: Potential difference is the measure of the work done to move a unit charge from one point to another in an electric field. It is the voltage drop across components like resistors, capacitors, or between two points in a circuit.
- **Occurrence**: Potential difference is observed across any electrical component or between any two points in a circuit when current is flowing. It represents the energy used or consumed as electrical energy travels through various parts of a circuit.
- **Measurement**: Like EMF, potential difference is also measured in volts (V). It can vary depending on the component and the current flowing through the circuit.
### Key Differences
1. **Nature**:
- **EMF**: It is a property of the source (battery, generator) and represents the maximum voltage the source can provide when no current is flowing.
- **Potential Difference**: It depends on the circuit elements and the current flowing through them. It reflects the actual voltage drop across a component.
2. **Condition**:
- **EMF**: Measured under open-circuit conditions (no current flowing).
- **Potential Difference**: Measured under closed-circuit conditions (current flowing).
3. **Role**:
- **EMF**: Provides the energy needed to drive current through the circuit.
- **Potential Difference**: Shows the energy used or converted in different parts of the circuit.
### Example to Illustrate
Consider a battery with an EMF of 12 volts connected to a circuit with a resistor. When the circuit is closed and current flows, the battery's EMF is responsible for pushing the current through the resistor. The voltage drop across the resistor is the potential difference. If the resistor is the only component in the circuit and has a resistance of 10 ohms with a current of 1.2 amps flowing through it, the potential difference across the resistor will be \( V = IR = 1.2 \times 10 = 12 \) volts.
In this simple case, the EMF of the battery is equal to the potential difference across the resistor because there are no other significant voltage drops in the circuit. However, in more complex circuits with multiple components, the EMF of a source may be different from the potential differences across individual components due to other resistances and voltage drops in the circuit.