Ohm's Law states that the current through a conductor between two points is directly proportional to the voltage across the two points, provided that the temperature remains constant. However, Ohm's Law is not universally applicable under all conditions, particularly at very low temperatures. Here's why:
### 1. **Material Properties Change:**
At extremely low temperatures, the electrical properties of materials can undergo significant changes. For example, in many materials (especially metals), the resistivity decreases as the temperature lowers, due to the reduction in lattice vibrations that scatter electrons.
- **Superconductivity**: For some materials, when they reach a critical low temperature, they enter a state called *superconductivity*, where their electrical resistance drops to zero. In this state, Ohm's Law breaks down completely because the relationship between current and voltage is no longer linear. A superconductor can carry current without any applied voltage.
### 2. **Quantum Effects**:
At very low temperatures, quantum mechanical effects become dominant, especially in conductors or semiconductors. The behavior of electrons in such materials deviates from classical physics (which Ohm's Law is based on), and phenomena like *quantum tunneling* and *electron wave interference* can occur, where the electron's behavior cannot be accurately described by Ohm's Law.
### 3. **Non-Linear Conduction**:
In some materials, at low temperatures, conduction becomes non-linear due to the effects of impurities, defects, or the atomic structure of the material itself. This non-linearity means the current is not proportional to the applied voltage, violating the assumption that Ohm’s Law holds.
### 4. **Semiconductor Behavior**:
In semiconductors, as the temperature drops, the number of thermally excited charge carriers (electrons and holes) decreases. This reduction in charge carriers can cause the material to behave more like an insulator, and the current may not follow a simple linear relationship with voltage, which violates Ohm’s Law.
### 5. **Phonon Scattering Reduction**:
At lower temperatures, there is reduced phonon scattering (the interaction between electrons and the vibrating atoms in a material), which affects the resistivity of the material. The drastic change in resistivity does not always allow for a simple application of Ohm's Law.
In summary, at very low temperatures, the behavior of materials often deviates from the conditions under which Ohm’s Law applies, mainly due to changes in the material's electrical properties, the onset of quantum effects, and the possible transition to superconductivity.