Ohm's Law states that the current (I) passing through a conductor is directly proportional to the voltage (V) across it and inversely proportional to the resistance (R) of the material, expressed as:
\[
V = I \times R
\]
For most materials, this relationship holds true under standard conditions of temperature and pressure. However, at **very low temperatures**, especially near absolute zero, certain materials exhibit unusual behavior where Ohm's Law may no longer apply as straightforwardly. There are several reasons for this:
### 1. **Superconductivity**
At very low temperatures, some materials enter a **superconducting state**, in which they exhibit **zero electrical resistance**. In this state:
- **Superconductors** allow current to flow without any voltage drop, which violates the basic premise of Ohm's Law that \( V = I \times R \), since \( R = 0 \).
- Once the material becomes superconducting, a current can flow indefinitely without the need for a continuous supply of voltage.
The critical temperature (known as the **transition temperature**) below which a material becomes superconducting varies, but it is usually very low, often close to **absolute zero (0 K or -273.15°C)**. Well-known superconducting materials include metals like lead, mercury, and alloys.
### 2. **Non-Linear Behavior of Semiconductors**
At very low temperatures, **semiconductors** behave differently compared to at room temperature. Normally, in semiconductors, the movement of charge carriers (electrons and holes) depends on thermal energy:
- As the temperature decreases, the number of thermally excited charge carriers in a semiconductor decreases drastically, leading to a situation where the current flow is no longer directly proportional to the voltage.
- This means that **Ohm’s Law fails** because the relationship between voltage and current becomes **non-linear** due to the lack of mobile charge carriers.
At extremely low temperatures, many semiconductors can behave more like insulators because the thermal energy is insufficient to promote electrons from the valence band to the conduction band.
### 3. **Quantum Effects in Conductors**
At temperatures close to absolute zero, **quantum mechanical effects** dominate the behavior of electrons in conductors. In this regime:
- **Electron transport** is no longer dominated by classical behavior, but rather by quantum tunneling and other effects, which can result in **non-linear current-voltage relationships**.
- Ohm's Law assumes that current flow is due to electrons scattering off impurities or lattice vibrations (phonons), which produce a constant resistance. But at low temperatures, **phonon activity is minimal**, so electron behavior is governed more by quantum interference and coherence, not by scattering as it is at higher temperatures.
### 4. **Contact and Interface Resistance**
At very low temperatures, certain materials may experience changes at the **interfaces between different materials**. In particular:
- **Contact resistance** between a conductor and a device can become significant, and its behavior can become temperature-dependent.
- Interfaces between different materials can cause non-ohmic behavior, where resistance varies in a non-linear way with the applied voltage.
### 5. **Changes in Material Properties**
- Many materials undergo structural changes at low temperatures, which can alter their **resistive properties**. For example, the mobility of electrons or the density of charge carriers may change, which directly affects the resistance of the material.
- **Insulating materials** can undergo changes that make them more conductive or less conductive at extremely low temperatures, further complicating the application of Ohm’s Law.
### Summary
At very low temperatures, Ohm's Law is not applicable in certain cases due to phenomena like superconductivity, quantum effects, and the non-linear behavior of semiconductors. These effects lead to situations where the voltage-current relationship is no longer linear, as Ohm’s Law predicts. In superconductors, for example, the resistance becomes zero, causing current to flow without any applied voltage, while in semiconductors, the reduced thermal energy can prevent the creation of charge carriers necessary for current flow.
Thus, the classical understanding of Ohm's Law holds true primarily at **moderate temperatures** and under normal conditions but breaks down in these extreme low-temperature scenarios.