Yes, electromotive force (emf) can be higher than voltage, but it's important to understand what both terms mean and how they are related.
### 1. **Electromotive Force (emf)**:
- **Definition**: Emf is the total energy supplied per unit charge by a source, such as a battery or a generator. It is the potential difference (voltage) across the terminals of the source when no current is flowing.
- **Units**: The unit of emf is volts (V), just like voltage.
- **Ideal Condition**: Emf is often referred to as the "open-circuit voltage" because it represents the maximum voltage a source can supply without any current flowing through a circuit.
### 2. **Voltage**:
- **Definition**: Voltage is the potential difference between two points in a circuit. When current flows through a circuit, the voltage available across the source's terminals is usually lower than the emf because of internal resistance within the source (like a battery or generator).
- **Load Effects**: When a load is connected to a source, the voltage at the source's terminals can drop due to the internal resistance of the source. The larger the load current, the larger the voltage drop across this internal resistance.
### Relationship Between Emf and Voltage:
1. **Internal Resistance**: Most real sources of emf (like batteries) have some internal resistance. When current flows, part of the emf is "lost" inside the source due to this internal resistance.
- **Emf (E) = Voltage (V) + Voltage Drop Across Internal Resistance (Ir)**, where:
- \( E \) is the emf,
- \( V \) is the terminal voltage,
- \( I \) is the current,
- \( r \) is the internal resistance of the source.
This means that when no current flows (open-circuit), \( V = E \), so the terminal voltage equals the emf. But when current flows, \( V \) becomes less than \( E \) due to the voltage drop across the internal resistance.
2. **Example**: Consider a battery with an emf of 12 V and an internal resistance of 1 ohm. If no current is drawn, the voltage at the terminals of the battery is 12 V (same as the emf). However, if a 3 A current is drawn from the battery, the voltage drop across the internal resistance is \( Ir = 3 \times 1 = 3 \, \text{V} \). The terminal voltage would then be \( V = E - Ir = 12 - 3 = 9 \, \text{V} \).
In this case, the emf is 12 V, but the actual voltage available across the terminals is 9 V when current flows.
### When is Emf Higher Than Voltage?
- **Under Load**: When a source is supplying current to a load, the voltage measured across its terminals (voltage) will typically be lower than its emf due to the internal resistance. In this case, the emf is higher than the terminal voltage.
- **Open Circuit**: When there is no current flowing (open circuit), the voltage is equal to the emf.
### Summary:
- **Emf** is the maximum potential a source can provide, while **voltage** is the actual potential difference across the terminals when the source is connected to a load.
- Emf can be higher than the terminal voltage, especially when current flows through the circuit, because of losses due to internal resistance.