Yes, Potential Difference (PD) can be higher than Electromotive Force (EMF) under certain conditions. To understand this, let's break down what PD and EMF are and how they relate to each other.
### Definitions
1. **Electromotive Force (EMF)**: EMF is the maximum potential difference between two points in a circuit when no current is flowing. It's essentially the voltage provided by a source like a battery or a generator.
2. **Potential Difference (PD)**: PD is the voltage across two points in a circuit while current is flowing. It represents the energy per unit charge used between these two points.
### Relationship Between EMF and PD
In an ideal situation, the potential difference across a device or a component (like a resistor) would be equal to the EMF of the source. However, in real-world scenarios, this is not always the case due to internal resistance.
#### Internal Resistance of a Source
Real batteries or generators have internal resistance, denoted as \( r \). This internal resistance causes a voltage drop when current flows through the source.
**Key Equations:**
1. **EMF (E)**: The total voltage supplied by the source.
2. **PD across an external resistor (V)**: The voltage drop across an external component.
3. **Current (I)**: The current flowing through the circuit.
4. **Internal Resistance (r)**: The resistance within the power source.
The EMF of a source is given by:
\[ E = V + I \cdot r \]
Where \( V \) is the potential difference across the external load.
### When PD Can Be Higher Than EMF
If you have a source with a non-zero internal resistance, the potential difference across an external resistor can exceed the EMF if the external resistor is large enough relative to the internal resistance.
**Example:**
1. **Battery with Internal Resistance:**
- Assume a battery with an EMF of 12V and an internal resistance of 1Ω.
- If the battery is connected to an external resistor of 10Ω, the current through the circuit will be:
\[
I = \frac{E}{R_{\text{total}}} = \frac{12V}{10Ω + 1Ω} = \frac{12V}{11Ω} \approx 1.09A
\]
- The voltage drop across the internal resistance (1Ω) is:
\[
V_{\text{internal}} = I \cdot r = 1.09A \cdot 1Ω = 1.09V
\]
- The potential difference across the external resistor (10Ω) is:
\[
V_{\text{external}} = I \cdot R_{\text{external}} = 1.09A \cdot 10Ω = 10.9V
\]
In this case, the potential difference across the external resistor (10.9V) is close to the EMF (12V) minus the internal drop.
### Special Cases
1. **Open Circuit**: When no current is flowing (open circuit), the PD across the terminals of the source equals the EMF because there's no voltage drop due to internal resistance.
2. **High Internal Resistance**: If the internal resistance is significant compared to the load resistance, the PD across the load can be considerably less than the EMF, not more.
### Conclusion
While in most practical scenarios the potential difference across a load will be less than or equal to the EMF due to internal resistance, it is theoretically possible for the PD to exceed the EMF under certain conditions, particularly when considering idealized or theoretical situations.