The potential difference (or voltage) across the terminals of a battery is generally less than the electromotive force (emf) of the battery, but this is under typical circumstances where the battery is supplying current to an external circuit. Let me explain why this is the case.
### Understanding EMF and Potential Difference
**Electromotive Force (EMF):** The emf of a battery represents the maximum potential difference that the battery can provide when no current is flowing through it. It's essentially the voltage of the battery when it is in an open circuit.
**Potential Difference Across the Terminals:** This is the voltage measured across the battery terminals when it is connected to a circuit and current is flowing.
### Reasons for Potential Difference Being Less Than EMF
1. **Internal Resistance:** Batteries have internal resistance due to the materials and construction of the battery. When current flows through the battery, this internal resistance causes a voltage drop inside the battery itself. The potential difference \( V \) across the battery terminals can be expressed as:
\[
V = \text{EMF} - I \cdot r
\]
where:
- \(\text{EMF}\) is the electromotive force of the battery.
- \(I\) is the current flowing through the battery.
- \(r\) is the internal resistance of the battery.
Thus, as current increases, the voltage drop due to internal resistance \( I \cdot r \) increases, making the terminal potential difference less than the emf.
2. **Load Effects:** When a battery is connected to a load (like a resistor), the potential difference across the terminals is also affected by the resistance of the load and the internal resistance of the battery. The voltage drop across the internal resistance reduces the terminal voltage.
3. **Battery Chemistry and State:** Over time, as a battery discharges or ages, its internal resistance can increase, which further decreases the terminal voltage compared to the emf.
### Special Cases
- **No Current Flowing:** When there is no current flowing (open circuit), the potential difference across the battery terminals is equal to the emf. This is because there is no internal resistance drop when current is zero.
- **Short Circuit:** In an idealized short circuit situation (where resistance of the load is almost zero), the potential difference across the battery terminals approaches zero, since the entire emf is dropped across the internal resistance of the battery.
### Conclusion
In summary, the potential difference across the terminals of a battery is always less than or equal to its emf when the battery is connected to a circuit with current flowing. The difference between the potential difference and the emf is due to the internal resistance of the battery, which causes a voltage drop when current flows.