The
electrochemical series is a list of elements (or ions) arranged in order of their
electrode potentials. It shows how easily a substance can either lose electrons (oxidation) or gain electrons (reduction) in a chemical reaction.
In simple terms, the electrochemical series helps us understand which elements or ions are more likely to get reduced (gain electrons) and which ones are more likely to get oxidized (lose electrons).
Key points to understand:
- Electrode potential: It refers to the tendency of a substance to gain or lose electrons when it is part of an electrochemical reaction. A more positive electrode potential means the substance is more likely to gain electrons (get reduced). A more negative potential means it's more likely to lose electrons (get oxidized).
- Reduction happens at the cathode (gain of electrons) and oxidation happens at the anode (loss of electrons).
- The electrochemical series helps in predicting the direction of electron flow in a reaction and deciding which substances will react with each other.
Example:
In the electrochemical series, you’ll find that
hydrogen ions (H⁺) have a
standard electrode potential of 0 volts. If you compare it to another ion, like
zinc (Zn²⁺), which has a more negative potential, you can predict that zinc is more likely to lose electrons (oxidize) than hydrogen ions, which are more likely to gain electrons (reduce).
Example of elements in the electrochemical series:
- Most easily reduced (high positive potential): F₂, O₂, Au (gold)
- Most easily oxidized (low negative potential): Li, K, Na, Mg, Zn
This series is very useful in applications like
galvanic cells (batteries) and
electrolysis.