The terminal potential difference (TPD) and electromotive force (EMF) are closely related concepts in electrical circuits, but they represent different quantities.
### Electromotive Force (EMF)
1. **Definition**: EMF is the maximum potential difference that a source (like a battery or generator) can provide when no current is flowing. It is the work done per unit charge to move charges through the source, and it is measured in volts (V).
2. **Source Characteristic**: EMF represents the inherent capability of the source to provide energy to the circuit. It is a measure of the source’s ability to drive current through an external circuit.
### Terminal Potential Difference (TPD)
1. **Definition**: Terminal potential difference is the actual voltage measured across the terminals of the power source when current is flowing. It is the voltage available to the external circuit and is also measured in volts (V).
2. **Dependence on Current**: The TPD depends on the current flowing through the circuit and the internal resistance of the source. It is given by:
\[
\text{TPD} = \text{EMF} - I \times r
\]
where \( I \) is the current flowing through the circuit, and \( r \) is the internal resistance of the source.
### Relationship Between EMF and TPD
The relationship between EMF and TPD can be understood through the following points:
1. **Without Current Flow**: When no current is flowing (i.e., the circuit is open), the TPD is equal to the EMF of the source. This is because there is no voltage drop across the internal resistance.
2. **With Current Flow**: When current flows through the circuit, the TPD is less than the EMF due to the voltage drop across the internal resistance of the source. The greater the current, the greater the voltage drop, and therefore the smaller the TPD. This relationship is mathematically described by:
\[
\text{TPD} = \text{EMF} - I \times r
\]
where \( I \times r \) is the voltage drop across the internal resistance.
### Example
Consider a battery with an EMF of 12 V and an internal resistance of 1 Ω. If the battery is delivering a current of 2 A to the circuit, the TPD across the battery terminals can be calculated as follows:
\[
\text{TPD} = \text{EMF} - I \times r = 12 \text{ V} - (2 \text{ A} \times 1 \text{ Ω}) = 12 \text{ V} - 2 \text{ V} = 10 \text{ V}
\]
In this case, the terminal potential difference is 10 V, which is less than the EMF of 12 V due to the internal resistance of the battery.
### Summary
- **EMF**: The maximum potential difference of a source when no current flows.
- **TPD**: The actual potential difference across the terminals of the source when current flows, and it is always less than or equal to the EMF due to internal resistance.
Understanding the relationship between EMF and TPD is crucial in practical electrical circuits, as it helps in assessing the efficiency and performance of power sources.