The terms "emf" (electromotive force) and "terminal potential difference" are related but distinct concepts in electrical circuits:
1. **Emf (Electromotive Force):**
- **Definition:** Emf is the maximum potential difference provided by a source like a battery or generator when no current is flowing through the circuit. It represents the work done by the source to move a unit charge from one terminal to the other.
- **Source:** Emf is associated with the source of electrical energy, such as a battery, cell, or generator.
- **Measurement:** Emf is measured in volts and can be thought of as the "ideal" voltage of the source.
2. **Terminal Potential Difference:**
- **Definition:** Terminal potential difference is the actual voltage measured across the terminals of the source when a current is flowing. It is the potential difference available to the external circuit.
- **Effect of Internal Resistance:** Terminal potential difference is less than the emf due to the internal resistance of the source. The formula for terminal potential difference \( V \) is given by \( V = \text{emf} - I \times r \), where \( I \) is the current and \( r \) is the internal resistance of the source.
- **Measurement:** It reflects the real voltage available for the external circuit's use.
In summary, the emf is the intrinsic voltage of the source without any current, while the terminal potential difference is the voltage that is actually available when the circuit is active and accounts for the internal resistance of the source.