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What is the difference between emf and terminal potential?

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Best answer
Sure, let's break down the concepts of electromotive force (emf) and terminal potential in detail:

### Electromotive Force (emf)

**Definition:**
Electromotive force (emf) is a measure of the energy provided by a power source per unit charge. It represents the maximum potential difference between two points in a circuit when no current is flowing.

**Characteristics:**
1. **Source of Energy:** Emf is generated by a power source like a battery or generator. It arises from chemical reactions in batteries or mechanical work in generators.
2. **No Current Flow:** Emf is measured when no current is flowing in the circuit. In other words, it's the potential difference across the terminals of the power source when it is open-circuited.
3. **Internal Energy Conversion:** It reflects the energy conversion that occurs within the power source, such as chemical energy to electrical energy in a battery.

**Example:**
If a battery has an emf of 12 volts, it means that when the battery is not connected to a circuit, the potential difference between its terminals is 12 volts.

### Terminal Potential

**Definition:**
Terminal potential (also known as terminal voltage) is the actual potential difference between the terminals of a power source when a current is flowing through the circuit.

**Characteristics:**
1. **Current Flow:** Terminal potential is measured when the circuit is closed and current is flowing. It takes into account the internal resistance of the power source.
2. **Real Voltage:** It reflects the actual voltage available to the external circuit and can be less than the emf due to internal resistance.
3. **Voltage Drop:** When current flows through the internal resistance of a battery or power source, there is a voltage drop inside the source, which reduces the terminal potential.

**Example:**
If the same battery with an emf of 12 volts is connected to a circuit and current flows through it, the terminal potential might drop to 11.5 volts due to the internal resistance of the battery.

### Relationship Between emf and Terminal Potential

The relationship between emf (E) and terminal potential (V) can be expressed with the formula:

\[ V = E - Ir \]

where:
- \( V \) is the terminal potential,
- \( E \) is the emf,
- \( I \) is the current flowing through the circuit,
- \( r \) is the internal resistance of the power source.

**Explanation:**
- The terminal potential \( V \) is always less than the emf \( E \) because of the voltage drop across the internal resistance \( r \) when current \( I \) flows.
- As the current increases, the voltage drop across the internal resistance increases, further reducing the terminal potential.

### Summary

- **Emf** is the maximum potential difference provided by a power source when no current is flowing.
- **Terminal potential** is the actual potential difference available when the circuit is closed and current flows, and it is always less than the emf due to the internal resistance of the power source.
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Electromotive force (EMF) and terminal potential are concepts related to electrical circuits, but they represent different aspects of how electrical energy is supplied and used. Here’s a detailed breakdown of each and how they differ:

### Electromotive Force (EMF)

**Definition:**
- EMF is a measure of the energy provided by a source per unit charge. It's the work done to move a unit positive charge from one terminal of a source to another in an open circuit (i.e., when no current is flowing).

**Characteristics:**
- **Source of Energy:** EMF is produced by sources like batteries, generators, or any device that converts some form of energy into electrical energy.
- **Ideal Condition:** It’s the maximum potential difference between the terminals of a source when no current flows through the circuit (open circuit condition).
- **Unit:** The unit of EMF is volts (V).
- **Formula:** If \( \mathcal{E} \) represents EMF, the work done \( W \) to move charge \( Q \) is given by \( \mathcal{E} = \frac{W}{Q} \).

### Terminal Potential

**Definition:**
- Terminal potential (or terminal voltage) is the actual voltage measured across the terminals of a source when current is flowing through the circuit. It is the potential difference that is actually available for use in the circuit.

**Characteristics:**
- **Real Condition:** It represents the voltage across the terminals under load conditions (i.e., when current is flowing).
- **Effect of Internal Resistance:** The terminal potential is always less than the EMF because some voltage is lost due to the internal resistance of the source. The relationship between EMF (\( \mathcal{E} \)), terminal potential (\( V \)), current (\( I \)), and internal resistance (\( r \)) is given by:
  
  \[
  V = \mathcal{E} - Ir
  \]

- **Measurement:** It’s what you actually measure when you connect a voltmeter across the terminals of a source while current is flowing.

### Key Differences

1. **Condition of Measurement:**
   - **EMF:** Measured under open circuit conditions (no current).
   - **Terminal Potential:** Measured under load conditions (current flowing).

2. **Impact of Internal Resistance:**
   - **EMF:** Does not account for internal resistance.
   - **Terminal Potential:** Accounts for the voltage drop due to internal resistance of the source.

3. **Usage:**
   - **EMF:** Represents the maximum possible voltage the source can provide.
   - **Terminal Potential:** Represents the actual voltage available to the circuit, which is affected by the internal resistance of the source.

### Example

Consider a battery with an EMF of 12V and an internal resistance of 1 ohm. If the battery supplies a current of 2A to a circuit, the terminal potential would be:

\[
V = \mathcal{E} - Ir
\]
\[
V = 12V - (2A \times 1 \Omega) = 12V - 2V = 10V
\]

So, while the EMF of the battery is 12V, the terminal potential (the voltage you would actually measure across the battery terminals when the current is flowing) is 10V.

Understanding these concepts is crucial in electrical engineering and physics, as they help in designing circuits and predicting how real-world components will behave.
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