Sure, let's break down the concepts of electromotive force (emf) and terminal potential in detail:
### Electromotive Force (emf)
**Definition:**
Electromotive force (emf) is a measure of the energy provided by a power source per unit charge. It represents the maximum potential difference between two points in a circuit when no current is flowing.
**Characteristics:**
1. **Source of Energy:** Emf is generated by a power source like a battery or generator. It arises from chemical reactions in batteries or mechanical work in generators.
2. **No Current Flow:** Emf is measured when no current is flowing in the circuit. In other words, it's the potential difference across the terminals of the power source when it is open-circuited.
3. **Internal Energy Conversion:** It reflects the energy conversion that occurs within the power source, such as chemical energy to electrical energy in a battery.
**Example:**
If a battery has an emf of 12 volts, it means that when the battery is not connected to a circuit, the potential difference between its terminals is 12 volts.
### Terminal Potential
**Definition:**
Terminal potential (also known as terminal voltage) is the actual potential difference between the terminals of a power source when a current is flowing through the circuit.
**Characteristics:**
1. **Current Flow:** Terminal potential is measured when the circuit is closed and current is flowing. It takes into account the internal resistance of the power source.
2. **Real Voltage:** It reflects the actual voltage available to the external circuit and can be less than the emf due to internal resistance.
3. **Voltage Drop:** When current flows through the internal resistance of a battery or power source, there is a voltage drop inside the source, which reduces the terminal potential.
**Example:**
If the same battery with an emf of 12 volts is connected to a circuit and current flows through it, the terminal potential might drop to 11.5 volts due to the internal resistance of the battery.
### Relationship Between emf and Terminal Potential
The relationship between emf (E) and terminal potential (V) can be expressed with the formula:
\[ V = E - Ir \]
where:
- \( V \) is the terminal potential,
- \( E \) is the emf,
- \( I \) is the current flowing through the circuit,
- \( r \) is the internal resistance of the power source.
**Explanation:**
- The terminal potential \( V \) is always less than the emf \( E \) because of the voltage drop across the internal resistance \( r \) when current \( I \) flows.
- As the current increases, the voltage drop across the internal resistance increases, further reducing the terminal potential.
### Summary
- **Emf** is the maximum potential difference provided by a power source when no current is flowing.
- **Terminal potential** is the actual potential difference available when the circuit is closed and current flows, and it is always less than the emf due to the internal resistance of the power source.