The **terminal potential difference** and the **electromotive force (emf)** are two important concepts in electrical circuits, and they are closely related, but not the same. Here's a detailed explanation of their differences:
### 1. **Electromotive Force (emf)**:
- **Definition**: EMF is the total energy provided by a source, such as a battery or generator, to move one coulomb of charge around a complete circuit. It is the energy per unit charge supplied by the chemical reaction or mechanical work inside the source.
- **Ideal Condition**: EMF represents the maximum potential difference across the terminals of a source when **no current is flowing**, i.e., in an open circuit.
- **Unit**: Volts (V).
- **Representation**: It is typically represented by the symbol **ε**.
- **Cause**: It is due to the internal energy sources (chemical, mechanical, etc.) inside the cell or generator that drive the movement of charges.
For example, a 12 V battery has an emf of 12 volts, meaning it supplies 12 joules of energy for every coulomb of charge.
### 2. **Terminal Potential Difference**:
- **Definition**: The terminal potential difference is the actual voltage across the terminals of a source (like a battery) **when current is flowing** through the circuit.
- **Effect of Internal Resistance**: The terminal potential difference is usually **less than** the emf when the current flows through the circuit due to the **internal resistance** of the source. This internal resistance causes a voltage drop inside the battery or generator.
- **Unit**: Volts (V).
- **Relation to Current**: When a current is flowing, the terminal potential difference decreases because of the internal resistance, which leads to a voltage drop given by \( V = \varepsilon - Ir \), where:
- \( I \) = current
- \( r \) = internal resistance
If a battery has internal resistance \( r \) and delivers current \( I \), the terminal potential difference \( V \) can be calculated as:
\[ V = \varepsilon - Ir \]
### Key Differences:
1. **In Open Circuit (No Load)**:
- EMF and terminal potential difference are equal since no current flows, and there is no internal voltage drop.
2. **In Closed Circuit (Load Connected)**:
- The terminal potential difference is **less than** the emf because of the voltage drop across the internal resistance of the source.
3. **Internal Resistance Factor**:
- EMF is the theoretical voltage when no current flows, and internal resistance has no effect.
- Terminal potential difference accounts for internal resistance, reducing the voltage available to the external circuit when current is flowing.
### Summary:
- **EMF**: The maximum voltage a source can provide (open circuit, no current).
- **Terminal Potential Difference**: The actual voltage measured across the source terminals when a current flows (closed circuit, with internal resistance).