Electromotive Force (EMF) and potential difference are related concepts in electrical circuits, but they are not always equal. Understanding the difference between them requires a bit of exploration into what each term means and the contexts in which they are used.
### **Electromotive Force (EMF)**
1. **Definition**: EMF is the maximum potential difference that a source (like a battery or generator) can provide when no current is flowing. It represents the energy provided by the source per unit charge. EMF is essentially the work done by the source to move a unit charge from one terminal to the other.
2. **Source Characteristics**: The EMF of a source is a property of the source itself. For instance, a battery with an EMF of 12 volts means it can provide a maximum of 12 volts of potential difference when not connected to a circuit or when no current flows.
3. **Internal Resistance**: Real sources have internal resistance, which causes a difference between the EMF and the actual potential difference across the terminals when a current is flowing. This internal resistance can affect the actual voltage that appears across the terminals when the source is under load.
### **Potential Difference (Voltage)**
1. **Definition**: Potential difference, also known as voltage, is the difference in electric potential between two points in a circuit. It can be measured across any two points where charges are present and can be defined for parts of a circuit, such as across a resistor.
2. **Load Conditions**: When current flows through a circuit, the potential difference across the terminals of a source is generally less than the EMF due to the internal resistance of the source. The actual voltage across the terminals is what is observed in practical situations.
### **Relationship Between EMF and Potential Difference**
1. **Internal Resistance Effect**: The internal resistance of the source affects the potential difference across its terminals. If \( R_{\text{int}} \) is the internal resistance of the source and \( I \) is the current flowing through the circuit, then the potential difference \( V \) across the terminals is given by:
\[
V = \text{EMF} - I \cdot R_{\text{int}}
\]
This equation shows that the potential difference \( V \) is less than the EMF by an amount equal to the product of the current and the internal resistance.
2. **Circuit Example**: For instance, if you have a battery with an EMF of 12 volts and it has an internal resistance of 1 ohm, and the current flowing through the circuit is 2 amperes, the potential difference across the terminals of the battery is:
\[
V = 12\, \text{V} - (2\, \text{A} \times 1\, \Omega) = 12\, \text{V} - 2\, \text{V} = 10\, \text{V}
\]
Here, the potential difference is 10 volts, which is less than the EMF of 12 volts due to the voltage drop across the internal resistance.
### **Summary**
- **EMF** is the maximum potential difference a source can provide when no current is flowing.
- **Potential Difference** across a source when it is in use (with current flowing) is less than the EMF due to the internal resistance of the source.
- The difference between EMF and potential difference arises because the internal resistance of the source causes a drop in voltage when current flows.
In essence, EMF represents the ideal, maximum voltage available, while the potential difference is the actual voltage you measure across the terminals when the source is connected to a circuit and current is flowing.