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What is the relationship between potential difference and EMF?

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The relationship between potential difference (often referred to as voltage) and electromotive force (EMF) is an important concept in electricity and circuits:

- **EMF (Electromotive Force)**: This is the maximum potential difference that a source, such as a battery or generator, can provide when no current is flowing. It represents the energy supplied per unit charge by the source to move charges through the circuit.

- **Potential Difference**: This is the voltage across two points in a circuit when current is flowing. It represents the work done per unit charge to move charges between those two points.

In an ideal scenario with no internal resistance or other losses, the potential difference across the terminals of a source would equal the EMF of the source. However, in real-world situations, internal resistance of the source and other factors can cause the potential difference to be less than the EMF. The relationship can be expressed as:

\[ V = \text{EMF} - I \cdot r \]

where:
- \( V \) is the potential difference across the terminals.
- \( \text{EMF} \) is the electromotive force of the source.
- \( I \) is the current flowing through the circuit.
- \( r \) is the internal resistance of the source.

So, the potential difference is generally less than the EMF when current is flowing, due to the voltage drop caused by the internal resistance of the source.
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The relationship between potential difference (V) and electromotive force (EMF, ε) is foundational in understanding how electrical circuits work. Here’s a detailed breakdown of these concepts:

### Electromotive Force (EMF)

1. **Definition**: EMF is the total energy supplied per unit charge by a source like a battery or generator when no current is flowing. It’s the source’s ability to drive an electric current around a circuit.

2. **Source**: EMF is generated by various sources, including batteries, generators, and solar cells. It’s a measure of the work done by the source to move charge through the circuit.

3. **Expression**: In a simple battery, the EMF can be thought of as the voltage across the terminals when the circuit is open. Mathematically, it’s often expressed as:
   \[
   \text{EMF} (\epsilon) = \frac{\text{Work done (W)}}{\text{Charge (Q)}}
   \]
   where W is the work done to move charge Q.

### Potential Difference (Voltage)

1. **Definition**: Potential difference is the difference in electric potential between two points in a circuit. It’s the energy per unit charge that drives current through the components of a circuit.

2. **Across Components**: In a circuit, the potential difference is measured across various components, such as resistors, capacitors, or the load. It reflects how much energy is converted from electrical to other forms of energy (e.g., thermal in a resistor).

3. **Expression**: For any two points A and B in a circuit, the potential difference V is given by:
   \[
   V = \text{Potential at A} - \text{Potential at B}
   \]

### Relationship Between EMF and Potential Difference

1. **Internal Resistance**: In real-world applications, a battery or power source has internal resistance. When current flows, there is a voltage drop across this internal resistance. The potential difference across the terminals of the source (which is what you measure with a voltmeter) is less than the EMF due to this internal resistance. The relationship can be expressed as:
   \[
   V = \epsilon - I \cdot r_{\text{int}}
   \]
   where \( V \) is the potential difference, \( \epsilon \) is the EMF, \( I \) is the current, and \( r_{\text{int}} \) is the internal resistance of the source.

2. **Open Circuit**: When the circuit is open (no current flows), the potential difference across the terminals of the source equals the EMF.

3. **Loaded Circuit**: When the circuit is closed and current flows, the potential difference across the terminals will be less than the EMF by an amount proportional to the internal resistance and the current.

In summary, the EMF is the maximum potential difference the source can provide, but in practical situations with current flowing, the potential difference will be lower due to the internal resistance of the source.
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