Electric potential and electromotive force (emf) are related concepts in the study of electricity, but they describe different aspects of electric circuits.
### Electric Potential
**Electric potential** refers to the electric potential energy per unit charge at a specific point in space due to the presence of electric fields. It is a measure of the work needed to move a unit positive charge from a reference point (usually infinity) to a particular point in the electric field. The electric potential at a point is given by:
\[ V = \frac{U}{q} \]
where:
- \( V \) is the electric potential,
- \( U \) is the electric potential energy,
- \( q \) is the charge.
Electric potential is measured in volts (V), where 1 volt = 1 joule per coulomb (J/C).
### Electromotive Force (emf)
**Electromotive force (emf)** is a measure of the energy provided by a source like a battery or generator per unit charge as it moves through the external circuit. It represents the work done by the source to move charges from the negative terminal to the positive terminal within the source itself. The emf is not actually a force but a potential difference provided by the source.
For a battery or generator, the emf (\(\mathcal{E}\)) is defined as:
\[ \mathcal{E} = \frac{W}{q} \]
where:
- \( \mathcal{E} \) is the emf,
- \( W \) is the work done by the source,
- \( q \) is the charge.
### Relationship Between Electric Potential and Emf
1. **Potential Difference and emf**: The emf of a source is directly related to the potential difference between its terminals. In an ideal situation (where internal resistance is zero), the emf is equal to the potential difference across the terminals of the source when no current flows through the circuit. When the circuit is closed and current flows, the potential difference across the terminals will be less than the emf due to the internal resistance of the source.
2. **Internal Resistance Effect**: In a real source with internal resistance \(r\), the relationship between the emf (\(\mathcal{E}\)), terminal potential difference (\(V_{\text{terminal}}\)), and current (\(I\)) is given by:
\[ V_{\text{terminal}} = \mathcal{E} - I \cdot r \]
Here, \(V_{\text{terminal}}\) is the voltage across the terminals of the source when current \(I\) is flowing. The term \(I \cdot r\) represents the voltage drop due to the internal resistance of the source.
### Summary
- **Electric potential** is the potential energy per unit charge at a point in an electric field.
- **Electromotive force (emf)** is the energy per unit charge provided by a source to move charges through the circuit.
In essence, the emf of a source can be thought of as the "ideal" or maximum potential difference it can provide, while the electric potential is a more general term that describes the potential energy per charge at a specific location in the field.